Either edge of trim is painted with body color, and is where caulking is applied at most 90 degree angles. Painting trim only, cannot feasibly include caulking, as this fails and opens up over time. Most homes need new caulking when painting the exterior, and a close inspection can determine. You'll need a large compressor, not just the typical 20 gallon variety most of us have. This is a 60 gallon, vertical compressor with typically a 5+ hp motor. Then you'll need a decent paint gun (possibly 2; one for primer and one for color) which again is an expense. Then there's the question of where you'll paint the car. Renting a paint booth is best, but can be expensive and hard to find. You can always seal up your garage or shoot out in the wetted down driveway, but you'll inevitably get dirt and moisture into the paint. Solvent or oil-based paints are used where a tough, durable finish is required for interior and exterior timber, masonry and furniture - although, as mentioned above, the new generation of acrylics and multi-surface paints offers viable alternatives. In general, brushes need to be cleaned with turpentine or white spirit.
Plaster. New dry plaster in good condition, which is to be finished with a paint other than water paint, should be given a coat of primer-sealer and allowed to dry thoroughly before being inspected for uniformity of appearance. Variations in gloss and color differences in the case of tinted primers indicate whether or not the whole surface has been completely sealed. If not, a second coat of primer-sealer should be applied. If only a few "suction spots" are apparent, a second coat over these areas may be sufficient. Materials and their application, every paint manufacturers paint will vary. If you are freshening up old walls and painting back to the existing color, the product doesn't have to be high end or have good coverage. If you need to paint a dark color over light color or light color over dark, you may want to consider purchasing a top quality paint to avoid multiple coats. I suggest Valspar, Pittsburgh or Benjamin Moore top of the line wall paint. These brands work well for straight out of the bucket use and are application friendly. Sherwin Williams is not my first choice because the coverage is poor and you will have to apply multiple coats but, it does apply, fluently. If you find a product does not apply well, maybe it is to heavy and/or sagging on the wall, you may need to thin the paint with a little water, this will reduce the coverage but make the paint flow better and lay down nicer on the surface. I do recommend latex paints for all applications, these days a good high end latex is as good as oil paint and your tools clean up much easier, it will also be less harsh on the respiratory system. The only situation I recommend oil paint, is as a primer/stain blocker over stains that "bleed" through the paint. You can get a stain blocking oil primer in a convenient spray can and spot prime any trouble areas before painting and in the case you need to prime all of the wall due to smoke or water damage, I recommend getting it in gallons and rolling it on where the stains are present. Don't forget proper ventilation and/or a respirator when using the oil based primers! If paints have been allowed to stand and hard lumps or skin have formed, the skin or scum should be removed, after which the paint can be stirred and strained through screen wire or through one or two thicknesses of cheesecloth. When you plan with split complementary colors, you begin with a single reference color. Next, choose a color from either edge of the complementary color and use it. While the complementary color scheme is a little more obvious, this scheme can fail totally if you just use paler versions of your warm colors. By the same token, picking a a warm undertone for the main contrasting color and combining it with two cool tones will showcase the warm tone.