You scuff up existing paint for two reasons. First, you want to get rid of any oil, grease or dirt trapped in the top layer of paint. This is the stuff that cleaners and degreasers can't get off. The second reason to scuff is to set up a physical bond for the new primer and paint to adhere to. You want to give the old paint some tooth so the new sticks better.
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Intensity refers to a colors brightness or saturation. Intensity refers to how pure a color is. For instance, if you were to use cadmium red straight from the tube, it would have a high intensity. If you were to mix it with another color however, its intensity would be diminished.
Airless Tip: If you have somebody who can start masking off the trim, have them start on that while you convert the airless to a new color. When changing colors with an airless paint sprayer it is a good idea to have a second bucket filled half way with clean water. Place the intake hose in the clean water gently without getting the old color everywhere in the water. Take the tip out of the airless and spray all of the old paint out of the hose and back into its original paint bucket. Be careful when doing this that you recognize when the paint starts turning watery. When it does point the gun into the first bucket and spray until it looks pretty clean. It doesn't need to be perfectly clean. When it looks good, clean off the intake line in the clean bucket and get the old color off the intake line. Now place the intake line inside of your new trim paint.
"Boxing" is a good method of mixing paints. Since paint is a mixture of solids and liquids, it is important that it be mixed thoroughly before using. To do this, the greater portion of the liquid contents of the can should be poured in a clean bucket somewhat larger than the paint can. Then, with a stiff paddle, the settled pigment in the original container should be loosened and any lumps broken up. After this, mix the material in the container thoroughly, using a figure 8 motion, and follow with a lifting and beating motion. Continue stirring the mixture vigorously while slowly adding the liquid that was previously poured off the top. Complete the mixing by pouring the paint back and forth from one container to the other several times until the entire amount is of uniform consistency.
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Another popular color wheel called the Munsell color wheel, is slightly more involved. Instead of 6 basic colors, the Munsell wheel consists of ten colors: red, yellow-red, yellow, yellow-green, green, blue-green, blue, blue-violet, red-violet and violet.